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Kinetics of reaction of C36 dimer acids with diethylenetriamine and triethylenetetramine for reactive polyamides

✍ Scribed by Vijay Kale; H. Sumathi Vedanayagam; R. Subbarao; M. Bhagawant Rao


Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
340 KB
Volume
53
Category
Article
ISSN
0021-8995

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## Abstract The cluster [W~3~S~4~H~3~(dmpe)~3~]^+^ (1) (dmpe=1,2‐bis(dimethylphosphino)ethane) reacts with HX (X=Cl, Br) to form the corresponding [W~3~S~4~X~3~(dmpe)~3~]^+^ (2) complexes, but no reaction is observed when 1 is treated with an excess of halide salts. Kinetic studies indicate that th