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Kinetics of radical polymerization—XL. Investigation of the effect of molecule inhibitors in polymerization in solution

✍ Scribed by I. Tánczos; T. Földes-Berezsnich; F. Tüdös


Book ID
107753874
Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
287 KB
Volume
19
Category
Article
ISSN
0014-3057

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The effect of aromatic nitro compounds (s-trinitrobenzene, o-and p-dinitrobenzene) was studied on the polymerization of p-methyl styrene by dilatometric method, using AIBN initiator at 50°C. The value of the stoichiometric coefficient 01) and of the relative reactivity (kJ&) was determined. In bulk

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## Abstract The kinetics of free radical polymerizations of __N__‐acryloylpiperidine (NAPi) were studied in benzene (Bz) using 2,2′‐azobisisobutyronitrile (AIBN) as initiator. The activation energy was determined to be 111.7 kJ mol^−1^. The overall rate of polymerization of the NAPi‐AIBN‐Bz system

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brief report is given of the method of intermittent illumination and of the rotating sector polymerization instrument built in our laboratory. The solvent dependence of chain propagation and termination rate constants was investigated for the polymerization system styrene-benzene at 50. The observed

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Molecular mass distribution was investigated for the polymerization of styrene initiated by AIBN at 50 in the presence of various solvents. Two types of solvents were chosen; in one, there is no chain transfer to solvent (Bz, DMF) whereas in CC14 the chain transfer should be considered. The molecula