Kinetics of radical copolymerization—VIII Investigation of the effect of molecular inhibitors in copolymerization—1. Bulk copolymerization

✍ Scribed by I. Tánczos; T. Földes-Berezsnich; F. Tüdös

• Publisher: Elsevier Science
• Year: 1983
• Tongue: English
• Weight: 264 KB
• Volume: 19
• Category: Article
• ISSN: 0014-3057
• DOI: 10.1016/0014-3057(83)90030-7

✦ Synopsis

The stoichiometry of the inhibition reaction was studied in AN MA, AN St and MA St copolymerization systems in the presence of nitroso-type molecular inhibitors. According to our experiments, the stoichiometric coefficient of the inhibitor depends on the initial composition of monomers. The hot radical theory, elaborated for the inhibition of polymerization, was extended to the inhibited copolymerization; this theory made it possible to explain and to describe quantitatively the variation of experimental # value with the initial monomer composition.