The kinetics of gamma-radiation induced free radicals reactions in carbon tetrachloride solutions of cyclohexane, cyclooctane, and cyclododecane were studied in the range of 27-190ยฐC. The activation energies found were in the order c -C ~H I S > c -C I ~H ~~ > c-CaHl6, which was explained as due to
Kinetics of radiation-induced hydrogen abstraction by trichloromethyl radicals in the liquid phase. Secondary alcohols
โ Scribed by Feldman, Liviu; Alfassi, Zeev B.
- Book ID
- 120519834
- Publisher
- American Chemical Society
- Year
- 1981
- Tongue
- English
- Weight
- 404 KB
- Volume
- 85
- Category
- Article
- ISSN
- 0022-3654
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๐ SIMILAR VOLUMES
The kinetics of hydrogen abstraction from cyclohexene by CCI:1 radicals were studied in ('('I4 solution as a function of cyclohexene concentration and temperature in the range of 26-140OC. T h e CCI:r radicals were produced both by radiolysis of CC14 and by photolysis of CCI:$r. T h e rate constant
## Abstract The kinetics of the gammaโradiation induced free radical reactions in carbon tetrachloride solutions of 2,3โdimethylbutane (DMB) were studied in the temperature range 32โ118 ยฐC. The kinetics of the following reactions were measured: and the following rate constants expression was obtai
## Abstract The kinetics of the gammaโradiation induced freeโradical chain reaction in solutions of carbon tetrachloride in cyclohexane (RH) has been investigated in the temperature range of 303โ383ยฐK. Trichloromethyl radicals were produced by the reaction of radiolytically generated cyclohexyl rad
## Abstract The kinetics of the gammaโradiation induced freeโradical chain reaction in solutions of carbon tetrachloride in __n__โhexane (RH) was investigated in the temperature range of 297.5โ373ยฐK. Trichloromethyl radicals were produced by the reaction of radiolytically generated hexyl radicals w
The kinetics of gamma-radiation-induced free-radical chain reactions in solutions of carbon tetrachloride in mixtures of varying composition of cyclohexane and n-hexane was investigated in the temperature range of 296"-413"K. Trichloromethyl radicals were produced by the reaction of radiolytically g