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Kinetics of radiation-induced hydrogen abstraction by trichloromethyl radicals in the liquid phase. Secondary alcohols

โœ Scribed by Feldman, Liviu; Alfassi, Zeev B.


Book ID
120519834
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
404 KB
Volume
85
Category
Article
ISSN
0022-3654

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## Abstract The kinetics of the gammaโ€radiation induced freeโ€radical chain reaction in solutions of carbon tetrachloride in __n__โ€hexane (RH) was investigated in the temperature range of 297.5โ€“373ยฐK. Trichloromethyl radicals were produced by the reaction of radiolytically generated hexyl radicals w

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The kinetics of gamma-radiation-induced free-radical chain reactions in solutions of carbon tetrachloride in mixtures of varying composition of cyclohexane and n-hexane was investigated in the temperature range of 296"-413"K. Trichloromethyl radicals were produced by the reaction of radiolytically g