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Kinetics of processes accompanying photoreduction of chloride complexes of Fe3+ in solid polymers

✍ Scribed by T.V. Pokholok; N.I. Zaitseva; G.B. Pariysky; D.Ya. Toptygin


Book ID
116092427
Publisher
Elsevier Science
Year
1982
Weight
823 KB
Volume
2
Category
Article
ISSN
0144-2880

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Free-radical degradation of solid poly(m
✍ T.V. Pokholok; G.B. Pariysky; N.I. Zaitseva; D.Ya. Toptygin πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 English βš– 619 KB

Almtract--The kinetics have been studied quantitatively and a mechanism proposed for the free-radical degradation of solid PMMA initiated by photoreduction of the chloride complexes of Fe 3+. The polymer was exposed in an inert atmosphere at 77 and 293 K to light of various spectral compositions wit