The kinetics of I-octene polymerization by the catalyst systems VO(acac),-AlEt, (I) and VO(acac),-AlEt,Br (II) was investigated. A linear dependence of the rate of polymerization on the monomer and catalyst concentrations as well as the overall activation energy of 44.5 kJ/mol for both the catalyst
β¦ LIBER β¦
Kinetics of Polymerization of 1-Octene with the Catalyst Systems Ticl 4 -Alet 3 or Alet 2 Br
β Scribed by Kothandaraman, H.; Devi, M. Saroja
- Book ID
- 121394658
- Publisher
- Taylor and Francis Group
- Year
- 1994
- Tongue
- English
- Weight
- 528 KB
- Volume
- 31
- Category
- Article
- ISSN
- 1060-1325
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## Abstract Kinetic studies of the polymerization of 1βoctene with the ZieglerβNatta catalyst systems VOCl~3~βAlEt~3~ (I) and VOCl~3~βAlEt~2~Br (II) are reported. The effect of the various parameters such as the Al/V ratio, catalyst and monomer concentrations, reaction time, aging time and temperat
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