The kinetics of propagation in the polymerization of propylene oxide proceeding by the activated monomer (AM) mechanism is studied. Propagation in this system involves addition of a protonated monomer molecule to the terminal hydroxyl group of the growing oligomer. A kinetic analysis of the reaction
Kinetics of polymerization by activated monomer mechanism
โ Scribed by Biedron, Tadeusz; Szymanski, Ryszard; Kubisa, Przemyslaw; Penczek, Stanislaw
- Book ID
- 119946307
- Publisher
- John Wiley and Sons
- Year
- 1990
- Tongue
- English
- Weight
- 380 KB
- Volume
- 32
- Category
- Article
- ISSN
- 1022-1360
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Cationic polymerization of 3,6-dibromo-9-(2,3-epoxypropyl)carbazole and 9-(2,3-epoxypropyl)carbazole in the presence of hydroxyl-containing compounds has been studied. It has been established that, at a high enough ratio of the concentrations of a hydroxyl-containing compound and monomer, polymeriza
## Abstract **Summary:** The polymerization of __ฮต__โcaprolactone (CL) in the presence of HClโยทโEt~2~O by an activated monomer mechanism was performed to synthesize diblock or triblock copolymers composed of poly(ethylene glycol) (PEG) and poly(__ฮต__โcaprolactone) (PCL). The obtained PCLs had molec