𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Kinetics of photochromic reactions in condensed phases

✍ Scribed by J. Sworakowski; K. Janus; S. Nešpůrek

Book ID
104011711
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
686 KB
Volume
116
Category
Article
ISSN
0001-8686

No coin nor oath required. For personal study only.

✦ Synopsis

A review of kinetic data reported for a few organic photochromic systems is given. The kinetics of processes taking place in solid matrices and in crystals was briefly discussed. The effect of solid matrices manifests itself in the kinetics being controlled by distributions rather than by discrete rate constants. The photochromic reactions often require a substantial free volume to occur, hence they seldom take place in crystals without a destruction of the crystal lattice. The activation energies of thermally driven reactions are in this case related rather to crystal parameters than to the reactions themselves.

📜 SIMILAR VOLUMES

Chemical dynamics in condensed phases: r
Chemical dynamics in condensed phases: relaxation, transfer and reactions in condensed molecular systems
✍ Abraham Nitzan 📂 Library 📅 2006 🏛 Oxford University Press 🌐 English ⚖ 3 MB

This text provides a uniform and consistent approach to diversified problems encountered in the study of dynamical processes in condensed phase molecular systems. Given the broad interdisciplinary aspect of this subject, the book focuses on three themes: coverage of needed background material, in-de