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Kinetics of peroxodisulphate oxidation of dicyanobis-(2,2′-bipyridyl)iron(II) and of the tetracyano-2,2′-bipyridylferrate(II) anion; initial state and transition state effects in reactions of tris-diimine and diimine-cyanide complexes of iron(II)

✍ Scribed by M.J. Blandamer; J. Burgess; N.V. Reed; P. Wellings


Book ID
118910574
Publisher
Elsevier Science
Year
1981
Weight
506 KB
Volume
43
Category
Article
ISSN
0022-1902

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✍ Lakshmanan Venkatasubramanian; Periasamy Dharmalingam; Pichai Maruthamuthu 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 501 KB

## Abstract Excitation of Ru(bipy)~3~^2+^ ion by visible radiation of wavelength λ = 436 nm in aqueous medium in presence of inorganic peroxides, peroxomonosulfate (PMS), peroxodisulfate (PDS), and peroxodiphosphate (PDP) was found to generate Ru(bipy)~3~^3+^. The kinetics of this photochemical oxi