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Kinetics of partly diffusion-controlled reaction XXI: A simple algorithm for computing the apparent rate of reaction

✍ Scribed by J. C. Andre; F. Baros; A. T. Reis E. Sousa

Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
614 KB
Volume
21
Category
Article
ISSN
0538-8066

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✦ Synopsis

Starting from Smoluchowski's hypothesis, a simple algorithm is developed in order to obtain the apparent rate constant at large values of time, t, with some physical and chemical processes, as in the case of diffusion controlled reactions. Some practical examples are illustrated, assuming nonuniform distribution function, space-dependent diffusion coefficient or short-range interaction leading to an asymptotic analytical expression of the form (Y + p/V?, where (Y and p are constants function of the system of interest.

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