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Kinetics of oxidation of chlorobenzenes and phenyl-ureas by Fe(II)/H2O2 and Fe(III)/H2O2. Evidence of reduction and oxidation reactions of intermediates by Fe(II) or Fe(III)

โœ Scribed by H Gallard; J De Laat


Book ID
117248155
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
497 KB
Volume
42
Category
Article
ISSN
0045-6535

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The role of Fe(II) species on the oxidat
โœ J.M. Santana-Casiano; M. Gonzรกlez-Dรกvila; F.J. Millero ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 227 KB

The oxidation of Fe(II) at nanomolar levels with O 2 , H 2 O 2 and their mixtures has been studied and a kinetic model has been applied to describe the experimental results. A first order pH dependence is obtained when the H 2 O 2 controls the oxidation, due to the large contributions of FeOH + and