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Kinetics of Oxidation of Benzyl Alcohol with Dilute Nitric Acid

โœ Scribed by Joshi, Sudhir R.; Kataria, Kamal L.; Sawant, Sudhirprakash B.; Joshi, Jyeshtharaj B.


Book ID
118012243
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
176 KB
Volume
44
Category
Article
ISSN
0888-5885

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We have studied the oxidation of benzyl alcohols by nitrous and nitric acid in sulfuric acid media. The oxidation by nitrous acid is rapid and has an activation energy of 10.6 -t 0.8 kcal mol-'. A Hammett plot of logkp vs. u -is linear with a p value of -1.4. The oxidation by nitric acid in sulfuric