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Kinetics of intramolecular electron exchange between phthalimide groups (PI) of the PI-CH2-(cyclohexane)-CH2-PI⨪ radical anions

✍ Scribed by K. Shimada; M. Szwarc


Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
401 KB
Volume
34
Category
Article
ISSN
0009-2614

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✦ Synopsis


We have determined at various temperatures the frequency of ihe intramolecular electron transfer between the phthalimide groups, (PI), of the radical anions PI-CHZ--(cycIohexsne)-CHz-PI-(in which the substituents are placed in the equatorial positions on carbon atoms 1 and 4 or 1 and 3 of the cyclohexane ring) and compared i: with the frequency of intramolecular exchange in the flexible radical anions PI-(CH2),-PI-and PI-(CHz)s -PI-, respectively.