Kinetics of hydrolytic polymerization of ε-caprolactam: 3. Formation of cyclic dimer
✍ Scribed by Yoshihiro Arai; Kazuo Tai; Hiroichi Teranishi; Takashi Tagawa
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 397 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0032-3861
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## Abstract A method to determine the concentration of ϵ‐aminocaproic acid (ACA) in poly‐ϵ‐caprolactam by high‐pressure liquid chromatography is established. The polymerizations for initial water concentrations of 0.42, 0.82, and 1.18 mol/kg and temperatures of 230, 240, 250, 260, 270, and 280°C we
## Abstract The concentrations of the cyclic oligomers (__C__~__i__~; __i__ = 3, 4, 5, and 6) in the polymeric products of ε‐caprolactam were determined by high‐performance liquid chromatography. The equilibrium data on the oligomers were obtained as a function of the polymerization temperature and