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Kinetics of hydrolysis of alkyl-bis-(γ-chloropropyl) phosphinates

✍ Scribed by V. E. Bel'skii; L. S. Andreeva; I. A. Aleksandrova; G. M. Vinokurova


Book ID
112421883
Publisher
Springer
Year
1970
Tongue
English
Weight
141 KB
Volume
19
Category
Article
ISSN
1573-9171

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Kinetic studies of hydrolysis of some al
✍ Tadashi Okuyama 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 287 KB

Hydrolysis reactions of methyl, ethyl, isopropyl, and t-butyl benzenesulfinates were kinetically investigated. Rates of alkaline hydrolysis decrease with increasing steric effects (Me > Et > i-Pr > t-Bu), while the t-butyl ester is the most reactive in perchloric acid (t-Bu > Me > E t => i-Fr). The