The kinetics of four gas-phase reactions involving halogenated methyl radicals (R,==CF,, CF2C1, CFCI,, and eel,) with molecular chlorine have been studied using a tuhular reactor coupled to a photoionization mass spectrometer. The radicals were homogeneously generated by the pulsed photolysis of pre
Kinetics of hydrogen abstraction reactions of CF3CHO, CF2ClCHO, CFCl2CHO and CCl3CHO with OH Radicals: An ab initio study
β Scribed by Chandra, Asit K.; Uchimaru, Tadafumi; Sugie, Masaaki
- Book ID
- 121331736
- Publisher
- Royal Society of Chemistry
- Year
- 2001
- Tongue
- English
- Weight
- 221 KB
- Volume
- 3
- Category
- Article
- ISSN
- 1463-9076
- DOI
- 10.1039/B104904F
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## Abstract The relative rate technique has been used to determine the rate constants of the reactions of OH radicals with CF~3~CClο£ΎCCl~2~ (__k__~1~), CF~3~CClο£ΎCClCF~3~ (__k__~2~) and CF~3~CFο£ΎCFCF~3~ (__k__~3~). Experiments were carried out at (298Β±2) K and atmospheric pressure using ultrapure nitr
An MP4 full,SDTQ r6-311qqG d,p rrMP2 full r6-311qq Ε½ . G d,p ab initio study was performed of the reactions of formyl and isoformyl cations with H O and NH , which play an important role in flame and 2 3 interstellar chemistries. Two different confluent channels were located leading to CO q H O q r