Kinetics of HNO reactions with O2 and HNO
β Scribed by M.G. Bryukov; A.A. Kachanov; R. Timonnen; J. Seetula; J. Vandoren; O.M. Sarkisov
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 576 KB
- Volume
- 208
- Category
- Article
- ISSN
- 0009-2614
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Flash photolysis of CH3CHO and H2CO in the presence of NO has been investigated by the intracavity laser spectroscopy technique. The decay of HNO formed by the reaction HCO + NO \* HNO + CO was studied a t NO pressures of 6.&380 torr. At low NO pressure HNO was found to decay by the reaction HNO + H
## Abstract The effects of NO on the decomposition of CH~3~ONO have been investigated in the temperature range 450β520 K at a constant pressure of 710 torr using He as buffer gas. The measured timeβdependent concentration profiles of CH~3~ONO, NO, N~2~O, and CH~2~O can be quantitatively accounted f
The reaction ( l a ) HO + HNO, -+ H,O + NO, (Ib) -+ H,O, + NO, has been studied using a discharge-flow tube with resonant fluorescence detection of HO. Measurements of k, have been made a t temperatures between 237 and 404 K. Our results and earlier work suggest that the rate constant has a minimum