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Kinetics of high-temperature oxidation of poly(diphenylphenylene oxide)

โœ Scribed by I.A. Serenkova; Yu.A. Shlyapnikov; C.R.H.I. de Jonge


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
174 KB
Volume
20
Category
Article
ISSN
0014-3057

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โœฆ Synopsis


Oxidation of poly(2,6-diphenylphenylene oxide) has been studied within the temperature range 380-470ยฐC. The process is autoaccelerated, the maximum rate of oxygen consumption is directly proportional to its pressure. Activation energy changes from 48 kJ/mol below 410': to 110 kJ/mol above 420 ยฐ. The oxidation rate below 410 (" depends on the molecular mass of the polymer.


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