## Abstract A kinetic model was used to predict the molecular weight developments and the critical properties in free‐radical crosslinking copolymerization. The predictions of the model were compared to the experimental data reported previously. Agreement of the kinetic model with experiments is sa
Kinetics of gelation in free radical crosslinking copolymerization
✍ Scribed by Oǧuz Okay
- Book ID
- 107847023
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 546 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0032-3861
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In order to evaluate the gelation behavior of macromonomeric azoinitiators (MIMs), the free radical polymerization of MIM and macrocrosslinkers (MCRs) have been compared. MIMs were synthesized by the reaction between 4,4'-dicyano-4,4'-azovaleryl chloride and poly(ethy1ene glyco1)s PEG-400, -1O00, -1
## Abstract A kinetic model is presented for prediction of the gel properties in free‐radical monovinyldivinyl monomer copolymerization. It is an extension of the kinetic model proposed recently for the sol species. The model involves the moment equations of the primary chains in the gel, and predi