Kinetics of free volume and physical aging in polymer glasses
โ Scribed by Chow, T. S.
- Book ID
- 124098916
- Publisher
- American Chemical Society
- Year
- 1984
- Tongue
- English
- Weight
- 576 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0024-9297
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๐ SIMILAR VOLUMES
Previous studies have documented the dramatic effects of film thickness, at least compared to the bulk state, and the more modest effects of aging temperature and polymer structure on physical aging of thin glassy polymer films. In this paper, these results are interpreted in terms of the free volum
We have investigated, in terms of the Cohen-Turnbull theory, a relationship for polycarbonate (PC) glasses between average stress relaxation times, ( t o ) , and average free volume sizes, (q), obtained from positron annihilation lifetime spectroscopy. This examination suggests that the minimum free