The kinetics of the permanganate oxidation of formic acid in aqueous perchloric acid a t 30Β°C were examined by the spectrophotometric method. The chemical reaction 2Mn0, A BHCOOH + 2H + -2Mn02 + 3C0, + 4H20. appears to proceed via several parallel reactions. The overall rate equation has been obtain
Kinetics of formic acid oxidation in advanced porous electrodes
β Scribed by Rudolf Holze; Ana-Maria Castro Luna
- Publisher
- Springer
- Year
- 1988
- Tongue
- English
- Weight
- 700 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0021-891X
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The electrochemical oxidation of porous lead electrodes is compared and contrasted with that of solid lead. Significant differences between the behaviours of the two electrode types are observed and interpreted in terms of the major component of the oxidation of the porous electrode arising from the
The oxidation of formic acid at a platinum electrode in 0.5 mol dm-j HsSO, was investigated by dc and cc methods. The oxidation rate of formic acid was approximately independent of the potential at potentials above about 0.35V vs. rhe, when the blocking effect of adsorbed carbon monoxide was compens