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Kinetics of electron-transfer between cytochrome c and multicopper oxidases.

✍ Scribed by Takeshi Sakurai

Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
106 KB
Volume
47
Category
Article
ISSN
0162-0134

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Electron transfer between cytochrome c and metalloporphyrins at high exothermicities
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The electron-transfer rates between cytochrome c and the anion radical of two metalloporphyrins ZnTPPS and ZnTPPC (A,5 for the reaction is I .42 eV) have been measured by laser flash spectroscopy. The anion radicals were produced by reaction of the porphyrins with hydrated electrons which resulted f