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Kinetics of Electron Transfer at Pt Nanostructured Film Electrodes

โœ Scribed by Horswell, Sarah L.; O'Nei, Ian A.; Schiffrin, David J.


Book ID
120363621
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
197 KB
Volume
107
Category
Article
ISSN
0022-3654

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Oxygen evolution reaction at Rt electrodes in alkaline solutions is characterized by two linear E-log i relationships. At low current densities (cd), the Tafel slope is close to 60 mV, whereas at bigb cd, it is close to 120 mV. The rates at bigb cd are strongly affected by the presence of an anodic