✦ LIBER ✦

Kinetics of electrodeposition reactions in mixed solvents—A quantitative description

✍ Scribed by Krzysztof Maksymiuk

Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 584 KB
Volume: 38
Category: Article
ISSN: 0013-4686
DOI: 10.1016/0013-4686(93)80244-t

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✦ Synopsis

The literature data concerning electrochemical reactions of the type: M"+ + ne-+ M(Hg) in mixed solvents are analysed in terms of competition of water, organic solvent and the activated complex for the place on the electrode surface.

Model calculations show how the Gibbs energy of the reactant solvation and adsorption of the organic solvent modify the shape of the dependence of the standard rate constant vs. mixed solvent composition.

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