Kinetics of Crosslinking Vinyl Polymerization
โ Scribed by Chern, Chorng-Shyan; Poehlein, Gary W.
- Book ID
- 125834241
- Publisher
- Taylor and Francis Group
- Year
- 1990
- Tongue
- English
- Weight
- 584 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0360-2559
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract The kinetics of vinyl chloride and vinyl acetate emulsion polymerization are reexamined. The validity of Ugelstad's model for systems with high desorption rate is confirmed by simulating conversion histories for both systems at different initiator concentrations and particle numbers. On
## Abstract Vinyl chloride was polymerized in the presence of a small quantity of such crosslinking agents as diallyl esters and divinyl ethers in a suspension and an emulsion system, in order to prepare poly(vinyl chloride) having very high polymerization degree. In the case of suspension polymer
The UV-initiated RAFT polymerizations of a series of poly(ethylene glycol) dimethacrylates (PEGDMA) were investigated using differential scanning photocalorimetry (DPC) at room temperature. The rate of the RAFT system was much lower than that of a conventional free radical polymerization. A mild aut
Transport of free radicals out of latex particles into the aqueous phase plays an important role in the emulsion polymerization of vinyl acetate. This so-called "desorption" process involves chain transfer to monomer which generates a mobile an8 rather stable monomer-unit free radical followed by th