Kinetics of copper catalyzed oxidation of 2,3-dimercapto-1-propanol by molecular oxygen
β Scribed by Edward G. Rippie; Takeru Higuchi
- Publisher
- John Wiley and Sons
- Year
- 1962
- Tongue
- English
- Weight
- 362 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0022-3549
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π SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
The kinetics of Ru(VI)-catalyzed oxidation of 2-propanol by hexacyanoferrate(III) was investigated in alkaline media using a spectrophotometric technique. The reaction shows first order in [Ru(VI)], a Michaelis-Menten-type dependence on [2-propanol], a fractional order in [Fe(CN) 3Γ 6 ] and a compli
## Abstract To understand the chemistry of Cu(II)βNH~3~βS(IV)βO~2~ system, the kinetics of the oxidation of sulfur(IV) catalyzed by amminecopper(II) complexes has been studied in the ammoniaβbuffered solutions. Sulfur(IV) is oxidized to sulfate. The complexes, Cu(NH~3~)^2+^, Cu(NH~3~)~2~^2+^, and C