Kinetics of coordinated-base-catalyzed and free-base-catalyzed configurational conversions of a tetraamine macrocyclic ligand complex of copper(II)
β Scribed by Lee, Chung Shin; Chung, Chung Sun
- Book ID
- 125941994
- Publisher
- American Chemical Society
- Year
- 1984
- Tongue
- English
- Weight
- 660 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0020-1669
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract The kinetics of hydrolysis of Cu(II)βsalicylamide complex have been studied in sodium hydroxide solution (0.5 to 2.5M). The observed pseudoβfirstβorder rate constants vary according to the empirical equation 1/π~obs~ = __B__~1~ + __B__~2~/[ΕH] up to 2.0 M sodium hydroxide concentration.
A kinetic study of base-catalyzed hydrolysis of Cu(I1)-malonamide complex has been performed in sodium hydroxide solution (0.2-1.25M). The reaction follows an irreversible firstorder consecutive path: The variation of kl\* and kZhs with alkali concentration was found to be in good agreement with th