Apparently competing cleavage and rearrangement reactions in a series of molecular ions have been studied by ionization and appearance potential methods, and by determination of the electron energy dependence of both normal and metastable daughter ion peak intensities. The processes investigated wer
β¦ LIBER β¦
Kinetics of competing rearrangement reactions and direct bond cleavages a field ionization study
β Scribed by K. Levsen; H.D. Beckey
- Book ID
- 103124684
- Publisher
- Elsevier Science
- Year
- 1974
- Weight
- 969 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0020-7381
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A few simple atom-transfer reactions i.e., A q X y A Βͺ A y X q A are studied by quantum mechanical ab initio methods. Emphasis is given to the detailed analysis of density matrices rather than to the energetics. Results reveal that during these reactions a small free valence always develops on the m