Kinetics of color development in the Landolt ("iodine clock") reaction
β Scribed by Church, John A.; Dreskin, Sanford A.
- Book ID
- 121405879
- Publisher
- American Chemical Society
- Year
- 1968
- Tongue
- English
- Weight
- 401 KB
- Volume
- 72
- Category
- Article
- ISSN
- 0022-3654
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The gas phase reaction I, + HCOOCH, +HI + CH,I + CO, has been studied spectrophotometrically in a static system over the pressure ranges I, (6-39 torr) and HCOOMe (28-360 torr). In the temperature range 293-356', the initial rate of disappearance of I, is first order in [HCOOMe] and half-order in [I
A study has been made both of secondary reactions occurring during the reaction of 12 with GeH4, and of the direct reaction between 12 and GeH31. Both these studies show that the abstraction reaction I + GeH3I -GeHZI + HI occurs about 30 times faster than the reaction I + GeH4 -GeHe + HI in the temp