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Kinetics of chain aggregation of poly(methyl methacrylate) in isoamyl acetate

✍ Scribed by Nakata, Mitsuo; Nakagawa, Tomohide; Nakamura, Yoshiki; Wakatsuki, Syogo

Book ID
120831023
Publisher
American Institute of Physics
Year
1999
Tongue
English
Weight
385 KB
Volume
110
Category
Article
ISSN
0021-9606

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It has been found that methyl salicylate (MS) undergoes a photoinduced decarboxylation to form phenol with a quantum yield of ca. 8 x The reaction is first order and the rate constant is proportional to the irradiance used. An activation energy of 1.2 kcal/mol was determined. Computer simulations w