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Kinetics of catalytic oxidation of benzoin to benzil by alumina supported active MnO2

โœ Scribed by S. Azizian; A. Eftekhari-Bafrooei; H. Bashiri

Book ID
110171200
Publisher
Springer
Year
2010
Tongue
English
Weight
209 KB
Volume
51
Category
Article
ISSN
0023-1584

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Kinetics and mechanism of oxidation of b
Kinetics and mechanism of oxidation of benzoin by polymer-supported N-bromo-sulphonamide
โœ A.S. Kanade; G.S. Gokavi; M.M. Salunkhe ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 165 KB

The oxidation of benzoin by polymer-supported N-bromo-sulphonamide in acetonitrile and in the presence of sulphuric acid has been studied. The reaction is first order with respect to N-bromosulphonamide and hydrogen ion concentration. The rate law and a probable mechanism, involving generation of re