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Kinetics of Carbonyl Sulfide Hydrolysis. 2. Effect of n -Alkanes in Mixtures of Water + Hydrocarbon

✍ Scribed by Andersen, Wendy C.; Bruno, Thomas J.


Book ID
120636957
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
50 KB
Volume
42
Category
Article
ISSN
0888-5885

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We have carried out a kinetic study of the 4-pyridinecarboxaldehyde plus n-hexy-Iamine system, at 25T, in water-dioxan mixtures (0-608 v/v) and in the pH range pK, + 1.5 > pH > pK, -1.5, where pK, is the pK value of the conjugate acid of the amine. The results obtained could be interpreted in terms