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Kinetics of Bromine−Magnesium Exchange Reactions in Substituted Bromobenzenes

✍ Scribed by Shi, Lei; Chu, Yuanyuan; Knochel, Paul; Mayr, Herbert

Book ID
111980157
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
214 KB
Volume
74
Category
Article
ISSN
0022-3263

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✍ François Trécourt; Gilles Breton; Véronique Bonnet; Florence Mongin; Francis Mar 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 233 KB

Bromine-magnesium exchange using iPrMgCl in THF at room temperature on 2-, 3-and 4-bromopyridines allowed the synthesis of various functionalized pyridines. The methodology was successfully used for the synthesis of 4-azaxanthone. Moreover, single exchange reactions observed on 2,6-, 3,5-, 2,3-and 2