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Kinetics of base-catalyzed polymerization of epoxides in dimethyl sulfoxide and hexamethylphosphoric triamide

✍ Scribed by Price, Charles C.; Akkapeddi, Murali Krishna

Book ID: 120013966
Publisher: American Chemical Society
Year: 1972
Tongue: English
Weight: 444 KB
Volume: 94
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00766a053

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## Abstract Various kinds of NCA's were polymerized in dimethyl sulfoxide (DMSO). DL‐Alanine NCA polymerized at a fast rate without initiator, the rate being represented by __R__~__p__1~ = __k__[M]^1/2^. When the polymerization was carried out in chloroform in the presence of DMSO, the rate was rep