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Kinetics of acetyl radical formation from methyl radicals and carbon monoxide and crystal structures of two acetylcobalt complexes

โœ Scribed by Bakac, Andreja; Espenson, James H.; Young, Victor G.


Book ID
127151918
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
644 KB
Volume
31
Category
Article
ISSN
0020-1669

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Addition of methyl radicals to carbon mo
โœ K. W. Watkins; William W. Word ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 761 KB

## Abstract Chemically activated acetyl radicals, with an excitation energy of 78 kJ/mole, were formed by the addition of methyl radicals to carbon monoxide. At 273ยทK the pressure required to stabilize one half of the excited radicals was 500 torr. From measurements of the acetyl radical yield at p