The kinetics of absorption of oxygen in aqueous solutions of acidic chromous chloride and ammoniacal cuprous chloride were studied in a stirred cell. Both these reactions were found to be very fast and the theory of gas absorption accompanied by fast pseudo-m"' order reaction was used to analyse the
Kinetics of absorption of oxygen in aqueous solutions of cuprous chloride
โ Scribed by A.S. Jhaveri; M.M. Sharma
- Publisher
- Elsevier Science
- Year
- 1967
- Tongue
- English
- Weight
- 515 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0009-2509
No coin nor oath required. For personal study only.
โฆ Synopsis
The kinetics of absorption of oxygen in aqueous solutions of cuprous chloride (in acidic and neutral solutions) was studied in a glass stirred cell. The reactions were found to be second order with respect to cuprous chloride and first order with respect to oxygen. The reaction rate constants at 30ยฐC were found to be 295 (l/g mole)2 secl for 5 M HCl solution and 334 (i/g mole)2 set-l for 3.75 M NaCl solution. The activation energies were found to be 8.35 and 5.9 Kcal/mole for the acidic and neutral solutions, respectively. The effect of ionic strength on the rate constant for the acidic solution was also investigated.
๐ SIMILAR VOLUMES
Kinetic data are presented for the oxidation of melts containing cuprous chloride by gaseous oxygen at temperatures in the range 350-500ยฐC. The molten systems studied include the bii system CuCI-CIrCl~, the ternary system KCI-CuCl-CuCl~, and the quaternary system KCl-LaC&CuCI-CuCl2. The data are cor
The absorption and reaction of oxygen in aqueous alkaline solutions of sodium dithionite has been experimentally investigated in a novel gas-liquid contactor. The novel gas-lift bubble column contactor was used to study the kinetics over wide ranges of reactant concentrations, temperature, and pH. T
The rates of absorption of chlorine diluted with nitrogen into aqueous acidic solutions of ferrous chloride of various concentrations were measured at l&25,35 and 45ยฐC using a batlled agitated vessel operated batchwise. The experimental results were analysed with the chemical absorption theory based
## 4 Experimental Methodology To explain our results, we used the method of gas-liquid absorption accompanied by pseudo n th order irreversible