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Kinetics for exchange of imino protons in the d(C-G-C-G-A-A-T-T-C-G-C-G) double helix and in two similar helices that contain a G.cntdot.T base pair, d(C-G-T-G-A-A-T-T-C-G-C-G), and an extra adenine, d(C-G-C-A-G-A-A-T-T-C-G-C-G)

โœ Scribed by Pardi, Arthur; Morden, Kathleen M.; Patel, Dinshaw J.; Tinoco, Ingacio


Book ID
126149117
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
899 KB
Volume
21
Category
Article
ISSN
0006-2960

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Temperature-jump kinetics of the dC-G-T-
โœ Y. Gloria Chu; Ignacio Tinoco Jr. ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Wiley (John Wiley & Sons) ๐ŸŒ English โš– 587 KB

The activation energy for the helix-dissociation process was 68 f 2 kcal/mol for the G-T 12-mer and 74 f 3 kcal/mol for the 13-mer. Rate constants for recombination were near 105 s-'M-' in the temperature range from 32 to 47OC; for the dissociation process, the rate constants varied from 1 s-l near