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Kinetics and thermodynamics of the exchange reactions of peroxy radicals with hydroperoxides

โœ Scribed by T. G. Denisova

Book ID
110170882
Publisher
Springer
Year
2007
Tongue
English
Weight
195 KB
Volume
48
Category
Article
ISSN
0023-1584

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๐Ÿ“œ SIMILAR VOLUMES

The kinetics of the interaction of perox
The kinetics of the interaction of peroxy radicals. I. The Tertiary Peroxy Radicals
โœ Prakash S. Nangia; Sidney W. Benson ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 807 KB

Existing data on the self-reactions of tertiary peroxy radicals ROn has been reanalyzed and corrected to deduce Arrhenius parameters for both termination and nontermination paths. For R = t-Rutyl, these are logk,(M-'sec-') = 7.1 -(7.0/8) and logknt(A4-'sec-') = 9.4 -(9.0/0), respectively, different

The kinetics of the interaction of perox
The kinetics of the interaction of peroxy radicals. II. Primary and secondary alkyl peroxy
โœ Prakash S. Nangia; Sidney W. Benson ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 656 KB

## Abstract A chain mechanism is proposed to account for the very rapid termination reactions observed between alkyl peroxy radicals containing ฮฑโ€Cโ€”H bonds which are from 10^4^ to 10^6^ faster than the termination of tertiary alkyl peroxy radicals. The new mechanism is equation image with termina