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Kinetics and Substrate Selectivity of the Oxidation of Saturated Hydrocarbons by Adamantyl Cations in Sulfuric Acid

โœ Scribed by L. K. Volkova; E. S. Rudakov; A. V. Nikolaenko


Book ID
110429356
Publisher
Springer
Year
2003
Tongue
English
Weight
79 KB
Volume
39
Category
Article
ISSN
0040-5760

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The kinetics and mechanism of the reaction between nitrous acid and bromine are studied in dilute sulfuric acid medium, using both the stopped-flow method and conventional spectrophotometry. The partial reaction order with respect to Br 2 moderately differs from 1, showing a saturation at a higher c