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Kinetics and steric course of the acid hydrolysis of trans-(ammine)(diethylenetriamine)(dichloro)cobalt(III) cation

โœ Scribed by Couldwell, M. Claire.; House, D. A.


Book ID
126771593
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
906 KB
Volume
13
Category
Article
ISSN
0020-1669

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Kinetics of the alkaline hydrolysis of c
โœ Sultan I. Amer; John A. McLean Jr. ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 345 KB

The alkaline hydrolysis of cisand rrans-diacetatobis(l,2-propanediamine)cobalt(III) cations appears to follow a substitution nucleophilic unimolecular conjugate base mechanism. In these cations, the acetate ligands are replaced by hydroxide ion in a stepwise manner. Both isomers undergo complete hy