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Kinetics and stereochemistry of reaction of optically active 2-bromomercuributane with bromine in carbon tetrachloride

✍ Scribed by É. V. Uglova; T. B. Svetlanova; I. P. Beletskaya; O. A. Reutov


Book ID
112434953
Publisher
Springer
Year
1968
Tongue
English
Weight
63 KB
Volume
17
Category
Article
ISSN
1573-9171

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## Reactions of-( + )--(I R)-phenybthyl 2-quinolyl (R)- sulfbxide 7a and ( --)-(I R)-phenylethyl2-quinolyl (S)sulfbxide 7b with methylmagnesium bromide were examined. The reaction gave (R)-Z-(Z-phenyle-thy1)quinoline 9 as a ligand-coupling product, and a mixture of methyl(1R)-phenylethyl (R)and (S