## Abstract The particle nucleation mechanism in emulsion polymerization of styrene with a novel polyester emulsifier, 5‐sulfoisophthalic acid dimethyl ester sodium salt‐modified tetracarboxylic acid‐terminated polyester (SMTAPE), was investigated. The consumption of SMTAPE micelles was monitored b
✦ LIBER ✦
Kinetics and particle nucleation mechanism of St/BA/qBVPBr emulsifier-free cationic emulsion polymerization
✍ Scribed by Jinzhi Zhang; Shiyuan Cheng; Guohong Lu; Shigan Chai
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 467 KB
- Volume
- 111
- Category
- Article
- ISSN
- 0021-8995
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Emulsifier-free emulsion polymerization of styrene (St) and copolymerization of St and 4-vinyl pyridine (4VP) in the presence of ammonium persulfate were studied. A comparison between the two polymerization systems was made. It was found that there were big differences comparing polymerization rate,