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Kinetics and modeling of diethylene glycol bisallyl carbonate bulk polymerization

✍ Scribed by Iztok Hace; Janvit Golob; Matjaž Krajnc


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
589 KB
Volume
96
Category
Article
ISSN
0021-8995

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✍ Hans R. Kricheldorf; Martina Lossin; Andreas Mahler 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 518 KB

Cyclobis(diethy1ene glycol carbonate), (DEGC),, was synthesized by polycondensation of diethylene glycol with diethyl carbonate followed by thermal depolymerization of the crude polycarbonate in vacuo. BuSnCl,-initiated polymerizations of (DEGC)2 in chlorobenzene at 100 "C gave poor results. Therefo