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Kinetics and Mechanistic Studies of the Atmospheric Oxidation of Alkynes

✍ Scribed by Yeung, Laurence Y.; Pennino, Michael J.; Miller, Angela M.; Elrod, Matthew J.

Book ID
125493682
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
220 KB
Volume
109
Category
Article
ISSN
1089-5639

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## Abstract The oxidation of __trans__‐stilbene, phenylacetylene, and diphenylacetylene by Tl(OAc)~3~ in aqueous acetic acid medium in the presence of HClO~4~ follows the rate law in [H^+^] of 0.1–1.0__M__, the [H^+^] dependence below 0.1__M__ being marginal. The reactions are strongly dielectric