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Kinetics and mechanisms of the recombination of Zn2+, Co2+, and Ni2+ with the metal-depleted catalytic site of horse liver alcohol dehydrogenase

✍ Scribed by Gunter Schneider; Michael Zeppezauer


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
696 KB
Volume
18
Category
Article
ISSN
0162-0134

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Metal Complexes with Macrocyclic Ligands
✍ Liselotte Hertli; Thomas A. Kaden 📂 Article 📅 1974 🏛 John Wiley and Sons 🌐 German ⚖ 308 KB 👁 1 views

## Abstract The formation and dissociation kinetics of the pentaco‐ordinated Cu^2+^, Ni^2+^, Co^2+^ and Zn^2+^ complexes with 1,4,8,11‐tetramethyl‐1,4,8,11‐tetraazacyclotetradecane (4‐MeCyclam‐14) was studied by pH‐stat techniques and spectrophotometrically. The rates of the reactions between 4‐MeC