Kinetics and mechanisms of the reaction of oxalacetic acid with (H2O)5CrCH2CN2+
β Scribed by Sisley, M. J.; Jordan, Robert B.
- Book ID
- 127109810
- Publisher
- American Chemical Society
- Year
- 1991
- Tongue
- English
- Weight
- 760 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0020-1669
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π SIMILAR VOLUMES
The rate constants for the reaction of CN with NzO and COz have been measured by the laser dissociation/laser-induced fluorescence (two-laser pump-probe) technique at temperatures between 300 and 740 K. The rate of CN + NzO was measurable above 500 K, with a least-squares averaged rate constant, k =
## Abstract The reaction of H radical with C~2~H~5~CN has been studied using various quantum chemistry methods. The geometries were optimized at the B3LYP/6β311+G(d,p) and B3LYP/6β311++G(2d,2p) levels. The singleβpoint energies were calculated using G3 and BMCβCCSD methods based on B3LYP/6β311++G(2