Kinetics and mechanisms of CH radical reactions with fluoromethanes and carbon tetrachloride
โ Scribed by S. Zabarnick; J.W. Fleming; M.C. Lin
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 598 KB
- Volume
- 120
- Category
- Article
- ISSN
- 0301-0104
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Pulsed laser photolysis/laser-induced fluorescence (LIFI is utilized to measure absolute rate constants of CH radical reactions as a function of temperature and pressure. Multiphoton dissociation of CHBr, at 266 nm is employed for the generation of C H (X'I1) radicals. The C H radical relative conce
A metathetical reaction between carbon tetrachloride and toluene to give benzyl chloride and chloroform occurs at temperatures above 200ยฐC (k = 4.8 X 1Olo e-82,m/RT cc mole-'sec-'). The reaction does not involve free radicals, as is shown by the kinetic behavior of the system, by the lack of effect