Kinetics and Mechanism of the Outer-Sphe
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Manuela Körner; Rudi van Eldik
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Article
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1999
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John Wiley and Sons
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English
⚖ 360 KB
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Keywords: Cytochrome c / Chromium(v) / Saturation kinetics / Separation of K and k ET / Volume profile / Kinetics The irreversible outer-sphere electron-transfer reaction High-pressure experiments were performed at two different pH values. The kinetic (stopped-flow) and thermodynamic between trans-