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Kinetics and mechanism of water substitution in the low-spin Fe(ii) complex of 4-octasulfophenylpyrazinoporphyrazineElectronic supplementary information (ESI) available: A total of ten figures including 1H NMR spectra, kinetic traces, Eyring plots and plots of kobs as a function of pressure. See http://www.rsc.org/suppdata/dt/b3/b311695f/

✍ Scribed by Kudrik, Evgeny V.; van Eldik, Rudi; Makarov, Sergei V.

Book ID: 120199234
Publisher: Royal Society of Chemistry
Year: 2004
Tongue: English
Weight: 213 KB
Volume: 3
Category: Article
ISSN: 1477-9226
DOI: 10.1039/B311695F

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1H-1,3-Diazepines, 5H-1,3-diazepines, 1,3-diazepinones, and 2,4-diazabicyclo[3.2.0]heptenesPreliminary reports on parts of this work have been published in ref 1. This paper is Diazepines, Part 3. For Part 2, see ref 2.,Electronic supplementary information (ESI) available: NMR spectra of 4a, 4c, 19v ? 20, 19a ? 25a, and 19g ? 25g (Fig. S1?S6), Arrhenius and Eyring plots for H-exchange in 4b,c (Fig. S7), views of the X-ray crystal structures of compounds 26 and 22bB (Fig. S8?S9), bond lengths and angles for compounds 4k, 22bB and 26, preparative procedures and characterization data for all compounds not described in the Experimental section, and computational data (Cartesian coordinates, absolute energies, IR, 1H and 13C NMR) for 20a?c, 21a?b, 22aA?F and 22aB dimer. See http://www.rsc.org/suppdata/ob/b3/b317099c/

✍ Reisinger, Ales; Koch, Rainer; Bernhardt, Paul V.; Wentrup, Curt 📂 Article 📅 2004 🏛 Royal Society of Chemistry 🌐 English ⚖ 496 KB