## Abstract The oxidation of six aliphatic aldehydes by tetrabutylammonium tribromide (TBATB) in aqueous acetic acid resulted in the formation of corresponding carboxylic acids. The reaction is first order with respect to TBATB and the aldehydes. The oxidation of deuteriated acetaldehyde (MeCDO) sh
Kinetics and mechanism of vanadium(IV) oxidation by tetrabutylammonium tribromide
β Scribed by Vilasrao A. Kalantre; Sanjeev P. Maradur; Gavisiddappa S. Gokavi
- Publisher
- Springer
- Year
- 2007
- Tongue
- English
- Weight
- 218 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0340-4285
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The oxidation of selenium(IV) by permanganate has been studied kinetically in acid, neutral and alkaline media. The reaction exhibits unit-order dependence on selenium(IV) and permanganate in all the three media. Manganese(VI) retards the reaction in alkaline medium. The rate-limiting step is the sa